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Electrocatalytic and Solar‐Driven CO(2) Reduction to CO with a Molecular Manganese Catalyst Immobilized on Mesoporous TiO(2)
Electrocatalytic CO(2) reduction to CO was achieved with a novel Mn complex, fac‐[MnBr(4,4′‐bis(phosphonic acid)‐2,2′‐bipyridine)(CO)(3)] (MnP), immobilized on a mesoporous TiO(2) electrode. A benchmark turnover number of 112±17 was attained with these TiO(2)|MnP electrodes after 2 h electrolysis. P...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5074277/ https://www.ncbi.nlm.nih.gov/pubmed/27110904 http://dx.doi.org/10.1002/anie.201601038 |