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Mixed Anhydride Intermediates in the Reaction of 5(4H)‐Oxazolones with Phosphate Esters and Nucleotides

5(4H)‐Oxazolones can be formed through the activation of acylated α‐amino acids or of peptide C termini. They constitute potentially activated intermediates in the abiotic chemistry of peptides that preceded the origin of life or early stages of biology and are capable of yielding mixed carboxylic‐p...

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Detalles Bibliográficos
Autores principales: Liu, Ziwei, Rigger, Lukas, Rossi, Jean‐Christophe, Sutherland, John D., Pascal, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5074369/
https://www.ncbi.nlm.nih.gov/pubmed/27534830
http://dx.doi.org/10.1002/chem.201602697