Unusual reactions of diazocarbonyl compounds with α,β-unsaturated δ-amino esters: Rh(II)-catalyzed Wolff rearrangement and oxidative cleavage of N–H-insertion products

Rh(II)-сatalyzed reactions of aroyldiazomethanes, diazoketoesters and diazodiketones with α,β-unsaturated δ-aminoesters, in contrast to reactions of diazomalonates and other diazoesters, give rise to the Wolff rearrangement and/or oxidative cleavage of the initially formed N–H-insertion products. Th...

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Detalles Bibliográficos
Autores principales: Nikolaev, Valerij A, Medvedev, Jury J, Galkina, Olesia S, Azarova, Ksenia V, Schneider, Christoph
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5082446/
https://www.ncbi.nlm.nih.gov/pubmed/27829897
http://dx.doi.org/10.3762/bjoc.12.180

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5082446/
https://www.ncbi.nlm.nih.gov/pubmed/27829897
http://dx.doi.org/10.3762/bjoc.12.180

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