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Real‐time Analysis of a Working Triethylaluminium‐Modified Cr/Ti/SiO(2) Ethylene Polymerization Catalyst with In Situ Infrared Spectroscopy

A diffuse reflectance infrared Fourier‐transform (DRIFT) study has been conducted at 373 K and 1 bar on an industrial Cr/Ti/SiO(2) Phillips‐type catalyst modified with, and without, triethylaluminium (TEAl) as co‐catalyst. The reaction rate of the polymerization of ethylene, as monitored by the incr...

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Detalles Bibliográficos
Autores principales: Cicmil, Dimitrije, Meeuwissen, Jurjen, Vantomme, Aurélien, Weckhuysen, Bert M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5084731/
https://www.ncbi.nlm.nih.gov/pubmed/27840661
http://dx.doi.org/10.1002/cctc.201600200