Synthesis of Calcium(II) Amidinate Precursors for Atomic Layer Deposition through a Redox Reaction between Calcium and Amidines

We have prepared two new Ca(II) amidinates, which comprise a new class of ALD precursors. The syntheses proceed by a direct reaction between Ca metal and the amidine ligands in the presence of ammonia. Bis(N,N′‐diisopropylformamidinato)calcium(II) (1) and bis(N,N′‐diisopropylacetamidinato)calcium(II...

Descripción completa

Detalles Bibliográficos
Autores principales: Kim, Sang Bok, Yang, Chuanxi, Powers, Tamara, Davis, Luke M., Lou, Xiabing, Gordon, Roy G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5094530/
https://www.ncbi.nlm.nih.gov/pubmed/27351794
http://dx.doi.org/10.1002/anie.201602406

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5094530/
https://www.ncbi.nlm.nih.gov/pubmed/27351794
http://dx.doi.org/10.1002/anie.201602406

Ejemplares similares