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Crystal structures of di-μ-bromido-bis{di­bromido­[η(5)-2-(di­methyl­amino)­inden­yl]zirconium(IV)} and di­bromido­bis­[η(5)-2-(di­methyl­amino)­inden­yl]zirconium(IV)

In the title compounds, [Zr(2)Br(6)(C(11)H(12)N)(2)], (I) and [ZrBr(2)(C(11)H(12)N)(2)], (II), the positions of the η(5)-binding 2-di­methyl­amino­indenyl units are fixed by intra­molecular C—H⋯Br inter­actions involving aromatic or di­methyl­amino H atoms. The binuclear mol­ecule of (I) is located...

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Detalles Bibliográficos
Autores principales: Medvedev, Michael G., Borisov, Ilya S., Kulyabin, Pavel S., Izmer, Vyatcheslav V., Kononovich, Dmitry S., Uborsky, Dmitry V., Voskoboynikov, Alexander Z.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095842/
https://www.ncbi.nlm.nih.gov/pubmed/27840717
http://dx.doi.org/10.1107/S2056989016016595