On the Ambiphilic Reactivity of Geometrically Constrained Phosphorus(III) and Arsenic(III) Compounds: Insights into Their Interaction with Ionic Substrates

The ambiphilic nature of geometrically constrained Group 15 complexes bearing the N,N‐bis(3,5‐di‐tert‐butyl‐2‐phenolate)amide pincer ligand (ONO(3−)) is explored. Despite their differing reactivity towards nucleophilic substrates with polarised element–hydrogen bonds (e.g., NH(3)), both the phosphor...

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Detalles Bibliográficos
Autores principales: Robinson, Thomas P., Lo, Siu‐Kwan, De Rosa, Daniel, Aldridge, Simon, Goicoechea, Jose M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095867/
https://www.ncbi.nlm.nih.gov/pubmed/27628576
http://dx.doi.org/10.1002/chem.201603135

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095867/
https://www.ncbi.nlm.nih.gov/pubmed/27628576
http://dx.doi.org/10.1002/chem.201603135

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