Clean thermal decomposition of tertiary-alkyl metal thiolates to metal sulfides: environmentally-benign, non-polar inks for solution-processed chalcopyrite solar cells

We report the preparation of Cu(2)S, In(2)S(3), CuInS(2) and Cu(In,Ga)S(2) semiconducting films via the spin coating and annealing of soluble tertiary-alkyl thiolate complexes. The thiolate compounds are readily prepared via the reaction of metal bases and tertiary-alkyl thiols. The thiolate complex...

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Detalles Bibliográficos
Autores principales: Heo, Jungwoo, Kim, Gi-Hwan, Jeong, Jaeki, Yoon, Yung Jin, Seo, Jung Hwa, Walker, Bright, Kim, Jin Young
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5101475/
https://www.ncbi.nlm.nih.gov/pubmed/27827402
http://dx.doi.org/10.1038/srep36608

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5101475/
https://www.ncbi.nlm.nih.gov/pubmed/27827402
http://dx.doi.org/10.1038/srep36608

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