X-ray Absorption and Emission Spectroscopic Studies of [L(2)Fe(2)S(2)](n) Model Complexes: Implications for the Experimental Evaluation of Redox States in Iron–Sulfur Clusters

[Image: see text] Herein, a systematic study of [L(2)Fe(2)S(2)](n) model complexes (where L = bis(benzimidazolato) and n = 2-, 3-, 4-) has been carried out using iron and sulfur K-edge X-ray absorption (XAS) and iron Kβ and valence-to-core X-ray emission spectroscopies (XES). These data are used as...

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Detalles Bibliográficos
Autores principales: Kowalska, Joanna K., Hahn, Anselm W., Albers, Antonia, Schiewer, Christine E., Bjornsson, Ragnar, Lima, Frederico A., Meyer, Franc, DeBeer, Serena
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5108557/
https://www.ncbi.nlm.nih.gov/pubmed/27097289
http://dx.doi.org/10.1021/acs.inorgchem.6b00295

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5108557/
https://www.ncbi.nlm.nih.gov/pubmed/27097289
http://dx.doi.org/10.1021/acs.inorgchem.6b00295

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