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A Porous Metal–Organic Framework Assembled by [Cu(30)] Nanocages: Serving as Recyclable Catalysts for CO(2) Fixation with Aziridines

Based on a novel ligand 5‐(2,6‐bis(4‐carboxyphenyl)pyridin‐4‐yl)isophthalic acid (H(4)BCP) with large skeletons, a unique porous framework {[Cu(2)(BCP)(H(2)O)(2)]·3DMF}(n) (1) assembled by nano‐sized and censer‐like [Cu(30)] cages is successfully obtained and structurally characterized. In 1, the la...

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Detalles Bibliográficos
Autores principales: Xu, Hang, Liu, Xiao‐Fang, Cao, Chun‐Shuai, Zhao, Bin, Cheng, Peng, He, Liang‐Nian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5111788/
https://www.ncbi.nlm.nih.gov/pubmed/27980985
http://dx.doi.org/10.1002/advs.201600048