Cargando…

Na@SiO(2)-Mediated Addition of Organohalides to Carbonyl Compounds for the Formation of Alcohols and Epoxides

Alcohols and epoxides were generated by the addition of organohalides to carbonyl compounds in the presence of sodium metal impregnated with silica gel (Na@SiO(2)) in THF at 25 °C through a radical pathway. Under the same conditions, Schiff bases were also successfully converted to the corresponding...

Descripción completa

Detalles Bibliográficos
Autores principales: Kapoor, Mohit, Hwu, Jih Ru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5113255/
https://www.ncbi.nlm.nih.gov/pubmed/27853277
http://dx.doi.org/10.1038/srep36225