Manganese(I)‐Catalyzed C−H Activation: The Key Role of a 7‐Membered Manganacycle in H‐Transfer and Reductive Elimination

Manganese‐catalyzed C−H bond activation chemistry is emerging as a powerful and complementary method for molecular functionalization. A highly reactive seven‐membered Mn(I) intermediate is detected and characterized that is effective for H‐transfer or reductive elimination to deliver alkenylated or...

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Detalles Bibliográficos
Autores principales: Yahaya, Nasiru P., Appleby, Kate M., Teh, Magdalene, Wagner, Conrad, Troschke, Erik, Bray, Joshua T. W., Duckett, Simon B., Hammarback, L. Anders, Ward, Jonathan S., Milani, Jessica, Pridmore, Natalie E., Whitwood, Adrian C., Lynam, Jason M., Fairlamb, Ian J. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5113680/
https://www.ncbi.nlm.nih.gov/pubmed/27603008
http://dx.doi.org/10.1002/anie.201606236

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5113680/
https://www.ncbi.nlm.nih.gov/pubmed/27603008
http://dx.doi.org/10.1002/anie.201606236

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