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Sterically Congested 2,6‐Disubstituted Anilines from Direct C−N Bond Formation at an Iodine(III) Center

2,6‐Disubstituted anilines are readily prepared from the direct reaction between amides and diaryliodonium salts. As demonstrated for 24 different examples, the reaction is of unusually broad scope with respect to the sterically congested arene and the nitrogen source, occurs without the requirement...

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Detalles Bibliográficos
Autores principales: Lucchetti, Nicola, Scalone, Michelangelo, Fantasia, Serena, Muñiz, Kilian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
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Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5113687/
https://www.ncbi.nlm.nih.gov/pubmed/27651117
http://dx.doi.org/10.1002/anie.201606599