DNA‐Accelerated Catalysis of Carbene‐Transfer Reactions by a DNA/Cationic Iron Porphyrin Hybrid

A novel DNA‐based hybrid catalyst comprised of salmon testes DNA and an iron(III) complex of a cationic meso‐tetrakis(N‐alkylpyridyl)porphyrin was developed. When the N‐methyl substituents were placed at the ortho position with respect to the porphyrin ring, high reactivity in catalytic carbene‐tran...

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Detalles Bibliográficos
Autores principales: Rioz‐Martínez, Ana, Oelerich, Jens, Ségaud, Nathalie, Roelfes, Gerard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5113691/
https://www.ncbi.nlm.nih.gov/pubmed/27730731
http://dx.doi.org/10.1002/anie.201608121

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5113691/
https://www.ncbi.nlm.nih.gov/pubmed/27730731
http://dx.doi.org/10.1002/anie.201608121

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