Hydrogenation of CO(2) to Formic Acid with a Highly Active Ruthenium Acriphos Complex in DMSO and DMSO/Water

The novel [Ru(Acriphos)(PPh(3))(Cl)(PhCO(2))] [1; Acriphos=4,5‐bis(diphenylphosphino)acridine] is an excellent precatalyst for the hydrogenation of CO(2) to give formic acid in dimethyl sulfoxide (DMSO) and DMSO/H(2)O without the need for amine bases as co‐reagents. Turnover numbers (TONs) of up to...

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Detalles Bibliográficos
Autores principales: Rohmann, Kai, Kothe, Jens, Haenel, Matthias W., Englert, Ulli, Hölscher, Markus, Leitner, Walter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5113777/
https://www.ncbi.nlm.nih.gov/pubmed/27356513
http://dx.doi.org/10.1002/anie.201603878

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5113777/
https://www.ncbi.nlm.nih.gov/pubmed/27356513
http://dx.doi.org/10.1002/anie.201603878

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