Contrasting Frustrated Lewis Pair Reactivity with Selenium‐ and Boron‐Based Lewis Acids

The activation of π‐bonds in diynyl esters has been investigated by using soft and hard Lewis acids. In the case of the soft selenium Lewis acid PhSeCl, sequential activation of the alkyne bonds leads initially to an isocoumarin (1 equiv PhSeCl) and then to a tetracyclic conjugated structure with th...

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Detalles Bibliográficos
Autores principales: Wilkins, Lewis C., Günther, Benjamin A. R., Walther, Melanie, Lawson, James R., Wirth, Thomas, Melen, Rebecca L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5113806/
https://www.ncbi.nlm.nih.gov/pubmed/27484052
http://dx.doi.org/10.1002/anie.201605239

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5113806/
https://www.ncbi.nlm.nih.gov/pubmed/27484052
http://dx.doi.org/10.1002/anie.201605239

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