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Computational Insights into Five- versus Six-Coordinate Iron Center in Ferrous Soybean Lipoxygenase

[Image: see text] Soybean lipoxygenase (SLO) serves as a prototype for fundamental understanding of hydrogen tunneling in enzymes. Its reactivity depends on the active site structure around a mononuclear, nonheme iron center. The available crystal structures indicate five-coordinate iron, while magn...

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Detalles Bibliográficos
Autores principales: Yu, Tao, Soudackov, Alexander V., Hammes-Schiffer, Sharon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5117133/
https://www.ncbi.nlm.nih.gov/pubmed/27532889
http://dx.doi.org/10.1021/acs.jpclett.6b01626