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Trigonal antiprismatic Co(ii) single molecule magnets with large uniaxial anisotropies: importance of Raman and tunneling mechanisms
The air-stable mononuclear Co(ii) compounds [Co(II)(Tpm)(2)][ClO(4)](2) (1, Tpm = tris(pyrazol-1-yl)methane), [Co(II)(Tpm)(2)][BPh(4)](2)·2MeCN (2) with trigonal antiprismatic geometry (trigonally elongated octahedral geometry) are reported. Magnetic and theoretical studies reveal that the complexes...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5125373/ https://www.ncbi.nlm.nih.gov/pubmed/27928492 http://dx.doi.org/10.1039/c6sc02035f |