Trigonal antiprismatic Co(ii) single molecule magnets with large uniaxial anisotropies: importance of Raman and tunneling mechanisms

The air-stable mononuclear Co(ii) compounds [Co(II)(Tpm)(2)][ClO(4)](2) (1, Tpm = tris(pyrazol-1-yl)methane), [Co(II)(Tpm)(2)][BPh(4)](2)·2MeCN (2) with trigonal antiprismatic geometry (trigonally elongated octahedral geometry) are reported. Magnetic and theoretical studies reveal that the complexes...

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Detalles Bibliográficos
Autores principales: Zhang, Yuan-Zhu, Gómez-Coca, Silvia, Brown, Andrew J., Saber, Mohamed R., Zhang, Xuan, Dunbar, Kim R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5125373/
https://www.ncbi.nlm.nih.gov/pubmed/27928492
http://dx.doi.org/10.1039/c6sc02035f

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