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Synthetically tuneable biomimetic artificial photosynthetic reaction centres that closely resemble the natural system in purple bacteria

Porphyrin-based photosynthetic reaction centre (PRC) mimics, ZnPQ-Q2HP-C(60) and MP(2)Q-Q2HP-C(60) (M = Zn or 2H), designed to have a similar special-pair electron donor and similar charge-separation distances, redox processes and photochemical reaction rates to those in the natural PRC from purple...

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Detalles Bibliográficos
Autores principales: Lee, Sai-Ho, Blake, Iain M., Larsen, Allan G., McDonald, James A., Ohkubo, Kei, Fukuzumi, Shunichi, Reimers, Jeffrey R., Crossley, Maxwell J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5125414/
https://www.ncbi.nlm.nih.gov/pubmed/27928494
http://dx.doi.org/10.1039/c6sc01076h