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2‐Diazo‐1‐phenyl‐2‐((trifluoromethyl)sulfonyl)ethan‐1‐one: Another Utility for Electrophilic Trifluoromethylthiolation Reactions

2‐Diazo‐1‐phenyl‐2‐((trifluoromethyl)sulfonyl)ethan‐1‐one (diazo‐triflone) (2) is not only a building block but also a reagent. In this study, diazo‐triflone, which was originally used for the synthesis of β‐lactam triflones as a trifluoromethanesulfonyl (SO(2)CF(3)) building block under catalyst‐fr...

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Detalles Bibliográficos
Autores principales: Huang, Zhongyan, Okuyama, Kenta, Wang, Chen, Tokunaga, Etsuko, Li, Xiaorui, Shibata, Norio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5126259/
https://www.ncbi.nlm.nih.gov/pubmed/27933224
http://dx.doi.org/10.1002/open.201500225