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cyclo‐P(4) Building Blocks: Achieving Non‐Classical Fullerene Topology and Beyond

The cyclo‐P(4) complexes [Cp(R)Ta(CO)(2)(η(4)‐P(4))] (Cp(R): Cp′′=1,3‐C(5)H(3)tBu(2), Cp′′′=1,2,4‐C(5)H(2)tBu(3)) turned out to be predestined for the formation of hollow spherical supramolecules with non‐classical fullerene‐like topology. The resulting assemblies constructed with CuX (X=Cl, Br) sho...

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Detalles Bibliográficos
Autores principales: Dielmann, Fabian, Peresypkina, Eugenia V., Krämer, Barbara, Hastreiter, Florian, Johnson, Brian P., Zabel, Manfred, Heindl, Claudia, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5129560/
https://www.ncbi.nlm.nih.gov/pubmed/27781348
http://dx.doi.org/10.1002/anie.201606074