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Asymmetric Induction by a Nitrogen (14)N/(15)N Isotopomer in Conjunction with Asymmetric Autocatalysis
Chirality arising from isotope substitution, especially with atoms heavier than the hydrogen isotopes, is usually not considered a source of chirality in a chemical reaction. An N (2) ,N (2) ,N (3) ,N (3)‐tetramethyl‐2,3‐butanediamine containing nitrogen ((14)N/(15)N) isotope chirality was synthesiz...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5132014/ https://www.ncbi.nlm.nih.gov/pubmed/27754589 http://dx.doi.org/10.1002/anie.201608955 |