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Hydroacenes Made Easy by Gold(I) Catalysis

A novel strategy for the synthesis of partially saturated acene derivatives has been developed based on a Au(I)‐catalyzed cyclization of 1,7‐enynes. This method provides straightforward access to stable polycyclic products featuring the backbone of the acene series, up to nonacene.

Detalles Bibliográficos
Autores principales: Dorel, Ruth, McGonigal, Paul R., Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5132091/
https://www.ncbi.nlm.nih.gov/pubmed/27381976
http://dx.doi.org/10.1002/anie.201604952