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The synthesis and crystal structure of 2-(chloro­selan­yl)pyridine 1-oxide: the first monomeric organoselenenyl chloride stabilized by an intra­molecular secondary Se⋯O inter­action

The title compound, C(5)H(4)ClNOSe, is the product of the reaction of sulfuryl chloride and 2-selanyl-1-pyridine 1-oxide in di­chloro­methane. The mol­ecule has an almost planar geometry (r.m.s. deviation = 0.012 Å), and its mol­ecular structure is stabilized by an intra­molecular secondary Se⋯O int...

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Detalles Bibliográficos
Autores principales: Askerov, Rizvan K., Matsulevich, Zhanna V., Borisova, Galina N., Zalepkina, Svetlana A., Smirnov, Vasiliy F., Grishina, Maria M., Dorovatovskii, Pavel V., Borisov, Alexander V., Khrustalev, Victor N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5137629/
https://www.ncbi.nlm.nih.gov/pubmed/27980851
http://dx.doi.org/10.1107/S2056989016018946