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Cadmium Compounds with an [N(3)C] Atrane Motif: Evidence for the Generation of a Cadmium Hydride Species
[Image: see text] Tris(2-pyridylthio)methane ([Tptm]H) has been employed to synthesize a series of cadmium carbatrane compounds that feature an [N(3)C] coordination environment. Specifically, [Tptm]H reacts with Cd[N(SiMe(3))(2)](2) to afford [Tptm]CdN(SiMe(3))(2), which thereby provides access to o...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2016
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5142449/ https://www.ncbi.nlm.nih.gov/pubmed/27934411 http://dx.doi.org/10.1021/acs.inorgchem.6b02196 |