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Amides Do Not Always Work: Observation of Guest Binding in an Amide-Functionalized Porous Metal–Organic Framework
[Image: see text] An amide-functionalized metal organic framework (MOF) material, MFM-136, shows a high CO(2) uptake of 12.6 mmol g(–1) at 20 bar and 298 K. MFM-136 is the first example of an acylamide pyrimidyl isophthalate MOF without open metal sites and, thus, provides a unique platform to study...
Autores principales: | , , , , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2016
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5152937/ https://www.ncbi.nlm.nih.gov/pubmed/27665845 http://dx.doi.org/10.1021/jacs.6b08059 |