Amides Do Not Always Work: Observation of Guest Binding in an Amide-Functionalized Porous Metal–Organic Framework

[Image: see text] An amide-functionalized metal organic framework (MOF) material, MFM-136, shows a high CO(2) uptake of 12.6 mmol g(–1) at 20 bar and 298 K. MFM-136 is the first example of an acylamide pyrimidyl isophthalate MOF without open metal sites and, thus, provides a unique platform to study...

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Detalles Bibliográficos
Autores principales: Benson, Oguarabau, da Silva, Ivan, Argent, Stephen P., Cabot, Rafel, Savage, Mathew, Godfrey, Harry G.W., Yan, Yong, Parker, Stewart F., Manuel, Pascal, Lennox, Matthew J., Mitra, Tamoghna, Easun, Timothy L., Lewis, William, Blake, Alexander J., Besley, Elena, Yang, Sihai, Schröder, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5152937/
https://www.ncbi.nlm.nih.gov/pubmed/27665845
http://dx.doi.org/10.1021/jacs.6b08059

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