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Switching from Controlled Ring-Opening Polymerization (cROP) to Controlled Ring-Closing Depolymerization (cRCDP) by Adjusting the Reaction Parameters That Determine the Ceiling Temperature

[Image: see text] Full control over the ceiling temperature (T(c)) enables a selective transition between the monomeric and polymeric state. This is exemplified by the conversion of the monomer 2-allyloxymethyl-2-ethyl-trimethylene carbonate (AOMEC) to poly(AOMEC) and back to AOMEC within 10 h by co...

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Detalles Bibliográficos
Autores principales: Olsén, Peter, Undin, Jenny, Odelius, Karin, Keul, Helmut, Albertsson, Ann-Christine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5155308/
https://www.ncbi.nlm.nih.gov/pubmed/27783494
http://dx.doi.org/10.1021/acs.biomac.6b01375