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Refining the reaction mechanism of O(2) towards its co-substrate in cofactor-free dioxygenases
Cofactor-less oxygenases perform challenging catalytic reactions between singlet co-substrates and triplet oxygen, in spite of apparently violating the spin-conservation rule. In 1-H-3-hydroxy-4-oxoquinaldine-2,4-dioxygenase, the active site has been suggested by quantum chemical computations to fin...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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PeerJ Inc.
2016
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5178339/ https://www.ncbi.nlm.nih.gov/pubmed/28028471 http://dx.doi.org/10.7717/peerj.2805 |