An Exceptionally Facile Two-Step Structural Isomerization and Detoxication via a Water-Assisted Double Lossen Rearrangement

N-hydroxyphthalimide (NHPI), which is best known as an organocatalyst for efficient C-H activation, has been found to be oxidized by quinoid compounds to its corresponding catalytically active nitroxide-radical. Here, we found that NHPI can be isomerized into isatoic anhydride by an unusually facile...

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Detalles Bibliográficos
Autores principales: Li, Feng, Huang, Chun-Hua, Xie, Lin-Na, Qu, Na, Shao, Jie, Shao, Bo, Zhu, Ben-Zhan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5180244/
https://www.ncbi.nlm.nih.gov/pubmed/28008985
http://dx.doi.org/10.1038/srep39207

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5180244/
https://www.ncbi.nlm.nih.gov/pubmed/28008985
http://dx.doi.org/10.1038/srep39207

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