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Conformation-driven quantum interference effects mediated by through-space conjugation in self-assembled monolayers
Tunnelling currents through tunnelling junctions comprising molecules with cross-conjugation are markedly lower than for their linearly conjugated analogues. This effect has been shown experimentally and theoretically to arise from destructive quantum interference, which is understood to be an intri...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5187444/ https://www.ncbi.nlm.nih.gov/pubmed/27996036 http://dx.doi.org/10.1038/ncomms13904 |