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Large Hyperpolarizabilities at Telecommunication-Relevant Wavelengths in Donor–Acceptor–Donor Nonlinear Optical Chromophores

[Image: see text] Octopolar D(2)-symmetric chromophores, based on the MPZnM supermolecular motif in which (porphinato)zinc(II) (PZn) and ruthenium(II) polypyridyl (M) structural units are connected via ethyne linkages, were synthesized. These structures take advantage of electron-rich meso-arylporph...

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Detalles Bibliográficos
Autores principales: Nayak, Animesh, Park, Jaehong, De Mey, Kurt, Hu, Xiangqian, Duncan, Timothy V., Beratan, David N., Clays, Koen, Therien, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5200929/
https://www.ncbi.nlm.nih.gov/pubmed/28058285
http://dx.doi.org/10.1021/acscentsci.6b00291