Rh-catalyzed reagent-free ring expansion of cyclobutenones and benzocyclobutenones

Here we report a reagent-free rhodium-catalyzed ring-expansion reaction via C–C cleavage of cyclobutenones. A variety of poly-substituted cyclopentenones and 1-indanones can be synthesized from simple cyclobutenones and benzocyclobutenones. The reaction condition is near pH neutral without additiona...

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Detalles Bibliográficos
Autores principales: Chen, Peng-hao, Sieber, Joshua, Senanayake, Chris H., Dong, Guangbin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5201212/
https://www.ncbi.nlm.nih.gov/pubmed/28042458
http://dx.doi.org/10.1039/c5sc01875g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5201212/
https://www.ncbi.nlm.nih.gov/pubmed/28042458
http://dx.doi.org/10.1039/c5sc01875g

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