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Disorder of the dimeric TCNQ–TCNQ unit in the crystal structure of [Ni(bpy)(3)](2)(TCNQ–TCNQ)(TCNQ)(2)·6H(2)O (TCNQ is 7,7,8,8-tetracyanoquinodimethane)
Crystallization from an aqueous methanol system composed of Ni(NO(3))(2), 2,2′-bipyridine (bpy) and LiTCNQ (TCNQ is 7,7,8,8-tetracyanoquinodimethane) in a 1:3:2 molar ratio yielded single crystals of bis[tris(2,2′-bipyridine-κ(2) N,N′)nickel(II)] bis(7,7,8,8-tetracyanoquinodimethane radica...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209759/ https://www.ncbi.nlm.nih.gov/pubmed/28083123 http://dx.doi.org/10.1107/S2056989016019162 |