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Crystal structure and absolute configuration of (3aR,3′aR,7aS,7′aS)-2,2,2′,2′-tetra­methyl-3a,6,7,7a,3′a,6′,7′,7′a-octa­hydro-4,4′-bi[1,3-benzodioxol­yl], obtained from a Pd-catalyzed homocoupling reaction

The absolute configuration, i.e. (3aR,3′aR,7aS,7′aS), of the title compound, C(18)H(26)O(4), synthesized via a palladium-catalyzed homocoupling reaction, was determined on the basis of the synthetic pathway and was confirmed by X-ray diffraction. The homocoupled mol­ecule is formed by two chemically...

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Detalles Bibliográficos
Autores principales: Macías, Mario A., Pandolfi, Enrique, Schapiro, Valeria, Silveira, Gustavo P., Vilela, Guilherme D., Suescun, Leopoldo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209778/
https://www.ncbi.nlm.nih.gov/pubmed/28083142
http://dx.doi.org/10.1107/S2056989016019927