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Crystal structure and absolute configuration of (3aR,3′aR,7aS,7′aS)-2,2,2′,2′-tetramethyl-3a,6,7,7a,3′a,6′,7′,7′a-octahydro-4,4′-bi[1,3-benzodioxolyl], obtained from a Pd-catalyzed homocoupling reaction
The absolute configuration, i.e. (3aR,3′aR,7aS,7′aS), of the title compound, C(18)H(26)O(4), synthesized via a palladium-catalyzed homocoupling reaction, was determined on the basis of the synthetic pathway and was confirmed by X-ray diffraction. The homocoupled molecule is formed by two chemically...
Autores principales: | Macías, Mario A., Pandolfi, Enrique, Schapiro, Valeria, Silveira, Gustavo P., Vilela, Guilherme D., Suescun, Leopoldo |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209778/ https://www.ncbi.nlm.nih.gov/pubmed/28083142 http://dx.doi.org/10.1107/S2056989016019927 |
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