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Crystal structure of a rare trigonal bipyramidal titanium(IV) coordination complex: trichlorido(3,3′-di-tert-butyl-2′-hydroxy-5,5′,6,6′-tetramethyl-1,1′-biphenyl-2-olato-κO (2))(tetrahydrofuran-κO)titanium(IV)

The title compound, [Ti(C(24)H(33)O(2))Cl(3)(C(4)H(8)O)], is a rare example of a trigonal–bipyramidal titanium coordination complex with three chloride and two oxygen donor ligands. The asymmetric unit contains two independent molecules having essentially the same conformation. The molecules featu...

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Detalles Bibliográficos
Autores principales:	Kim, Yun Young, Tanski, Joseph M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2017
Materias:	Research Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209780/ https://www.ncbi.nlm.nih.gov/pubmed/28083144 http://dx.doi.org/10.1107/S2056989016020156

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5209780/
https://www.ncbi.nlm.nih.gov/pubmed/28083144
http://dx.doi.org/10.1107/S2056989016020156

Crystal structure of a rare trigonal bipyramidal titanium(IV) coordination complex: tri­chlorido­(3,3′-di-tert-butyl-2′-hy­droxy-5,5′,6,6′-tetra­methyl-1,1′-biphenyl-2-olato-κO (2))(tetra­hydro­furan-κO)­titanium(IV)

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Crystal structure of a rare trigonal bipyramidal titanium(IV) coordination complex: trichlorido(3,3′-di-tert-butyl-2′-hydroxy-5,5′,6,6′-tetramethyl-1,1′-biphenyl-2-olato-κO (2))(tetrahydrofuran-κO)titanium(IV)