Diastereoselective Synthesis of Highly Substituted Tetrahydrofurans by Pd-Catalyzed Tandem Oxidative Cyclization–Redox Relay Reactions Controlled by Intramolecular Hydrogen Bonding

[Image: see text] Palladium-catalyzed oxidative cyclization of alkenols provides a convenient entry into cyclic ethers but typically proceeds with little or no diastereoselectivity for cyclization of trisubstituted olefins to form tetrahydrofurans due to the similar energies of competing 5-membered...

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Detalles Bibliográficos
Autores principales: Brooks, Joshua L., Xu, Liping, Wiest, Olaf, Tan, Derek S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5224347/
https://www.ncbi.nlm.nih.gov/pubmed/28004933
http://dx.doi.org/10.1021/acs.joc.6b02053

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5224347/
https://www.ncbi.nlm.nih.gov/pubmed/28004933
http://dx.doi.org/10.1021/acs.joc.6b02053

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