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Synthesis of γ-pyrones via decarboxylative condensation of β-ketoacids

ABSTRACT: This manuscript describes the convergent synthesis of aryl- and alkyl-disubstituted γ-pyrones from β-ketoacids. The reaction proceeds in the presence of trifluoromethanesulfonic anhydride via an unprecedented decarboxylative auto-condensation of the starting material. Herein, the scope and...

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Detalles Bibliográficos
Autores principales: Merad, Jérémy, Maier, Thomas, Rodrigues, Catarina A. B., Maulide, Nuno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Vienna 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5225206/
https://www.ncbi.nlm.nih.gov/pubmed/28127091
http://dx.doi.org/10.1007/s00706-016-1851-2