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First chemo-enzymatic synthesis of the (R)-Taniguchi lactone and substrate profiles of CAMO and OTEMO, two new Baeyer–Villiger monooxygenases

ABSTRACT: This study investigates the substrate profile of cycloalkanone monooxygenase and 2-oxo-Δ(3)-4,5,5-trimethylcyclopentenylacetyl-coenzyme A monooxygenase, two recently discovered enzymes of the Baeyer–Villiger monooxygenase family, used as whole-cell biocatalysts. Biooxidations of a diverse...

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Detalles Bibliográficos
Autores principales: Rudroff, Florian, Fink, Michael J., Pydi, Ramana, Bornscheuer, Uwe T., Mihovilovic, Marko D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Vienna 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5225235/
https://www.ncbi.nlm.nih.gov/pubmed/28127101
http://dx.doi.org/10.1007/s00706-016-1873-9