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Diastereoselective anodic hetero- and homo-coupling of menthol-, 8-methylmenthol- and 8-phenylmenthol-2-alkylmalonates

Diastereoselective radical coupling was achieved with chiral auxiliaries. The radicals were generated by anodic decarboxylation of five malonic acid derivatives. These were prepared from benzyl malonates and four menthol auxiliaries. Coelectrolyses with 3,3-dimethylbutanoic acid in methanol at plati...

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Detalles Bibliográficos
Autores principales: Letzel, Matthias C, Schäfer, Hans J, Fröhlich, Roland
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238534/
https://www.ncbi.nlm.nih.gov/pubmed/28179946
http://dx.doi.org/10.3762/bjoc.13.5