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Orthogonal protection of saccharide polyols through solvent-free one-pot sequences based on regioselective silylations

tert-Butyldimethylsilyl (TBDMS) and tert-butyldiphenylsilyl (TBDPS) are alcohol protecting groups widely employed in organic synthesis in view of their compatibility with a wide range of conditions. Their regioselective installation on polyols generally requires lengthy reactions and the use of high...

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Detalles Bibliográficos
Autores principales: Traboni, Serena, Bedini, Emiliano, Iadonisi, Alfonso
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238545/
https://www.ncbi.nlm.nih.gov/pubmed/28144345
http://dx.doi.org/10.3762/bjoc.12.271