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Electron-transfer-initiated benzoin- and Stetter-like reactions in packed-bed reactors for process intensification

A convenient heterogeneous continuous-flow procedure for the polarity reversal of aromatic α-diketones is presented. Propaedeutic batch experiments have been initially performed to select the optimal supported base capable to initiate the two electron-transfer process from the carbamoyl anion of the...

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Detalles Bibliográficos
Autores principales: Zaghi, Anna, Ragno, Daniele, Di Carmine, Graziano, De Risi, Carmela, Bortolini, Olga, Giovannini, Pier Paolo, Fantin, Giancarlo, Massi, Alessandro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238549/
https://www.ncbi.nlm.nih.gov/pubmed/28144342
http://dx.doi.org/10.3762/bjoc.12.268