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Direct arylation catalysis with chloro[8-(dimesitylboryl)quinoline-κN]copper(I)
We report direct arylation of arylhalides with unactivated sp(2) C–H bonds in benzene and naphthalene using a copper(I) catalyst featuring an ambiphilic ligand, (quinolin-8-yl)dimesitylborane. Direct arylation could be achieved with 0.2 mol % catalyst and 3 equivalents of base (KO(t-Bu)) at 80 °C to...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238606/ https://www.ncbi.nlm.nih.gov/pubmed/28144346 http://dx.doi.org/10.3762/bjoc.12.272 |