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Direct arylation catalysis with chloro[8-(dimesitylboryl)quinoline-κN]copper(I)

We report direct arylation of arylhalides with unactivated sp(2) C–H bonds in benzene and naphthalene using a copper(I) catalyst featuring an ambiphilic ligand, (quinolin-8-yl)dimesitylborane. Direct arylation could be achieved with 0.2 mol % catalyst and 3 equivalents of base (KO(t-Bu)) at 80 °C to...

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Detalles Bibliográficos
Autores principales:	Tamang, Sem Raj, Hoefelmeyer, James D
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2016
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5238606/ https://www.ncbi.nlm.nih.gov/pubmed/28144346 http://dx.doi.org/10.3762/bjoc.12.272

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