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Indefinitely stable iron(IV) cage complexes formed in water by air oxidation

In nature, iron, the fourth most abundant element of the Earth's crust, occurs in its stable forms either as the native metal or in its compounds in the +2 or +3 (low-valent) oxidation states. High-valent iron (+4, +5, +6) compounds are not formed spontaneously at ambient conditions, and the on...

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Detalles Bibliográficos
Autores principales: Tomyn, Stefania, Shylin, Sergii I., Bykov, Dmytro, Ksenofontov, Vadim, Gumienna-Kontecka, Elzbieta, Bon, Volodymyr, Fritsky, Igor O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5253674/
https://www.ncbi.nlm.nih.gov/pubmed/28102364
http://dx.doi.org/10.1038/ncomms14099