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Electron Transfer and Modification of Oligosilanylsilatranes and Related Derivatives
[Image: see text] Several silatranyl -substituted oligosilanes were prepared starting from bis(trimethylsilyl)silatranylsilanide. Electrochemical and theoretical investigations of some oligosilanes revealed that electrooxidation occurs by formation of a short-lived cation radical. This species under...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2016
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5264216/ https://www.ncbi.nlm.nih.gov/pubmed/28133409 http://dx.doi.org/10.1021/acs.organomet.6b00786 |