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Electron Transfer and Modification of Oligosilanylsilatranes and Related Derivatives

[Image: see text] Several silatranyl -substituted oligosilanes were prepared starting from bis(trimethylsilyl)silatranylsilanide. Electrochemical and theoretical investigations of some oligosilanes revealed that electrooxidation occurs by formation of a short-lived cation radical. This species under...

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Detalles Bibliográficos
Autores principales: Aghazadeh Meshgi, Mohammad, Baumgartner, Judith, Jouikov, Viatcheslav V., Marschner, Christoph
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5264216/
https://www.ncbi.nlm.nih.gov/pubmed/28133409
http://dx.doi.org/10.1021/acs.organomet.6b00786