Intramolecular 1,5-C(sp(3))–H radical amination via Co(ii)-based metalloradical catalysis for five-membered cyclic sulfamides

Co(ii)-based metalloradical catalysis (MRC) proves effective for intramolecular 1,5-C–H amination of sulfamoyl azides under neutral and nonoxidative conditions, providing a straightforward approach to access strained 5-membered cyclic sulfamides with nitrogen gas as the only byproduct. The metallora...

Descripción completa

Detalles Bibliográficos
Autores principales: Lu, Hongjian, Lang, Kai, Jiang, Huiling, Wojtas, Lukasz, Zhang, X. Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5271564/
https://www.ncbi.nlm.nih.gov/pubmed/28138382
http://dx.doi.org/10.1039/c6sc02231f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5271564/
https://www.ncbi.nlm.nih.gov/pubmed/28138382
http://dx.doi.org/10.1039/c6sc02231f

Ejemplares similares