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Intramolecular 1,5-C(sp(3))–H radical amination via Co(ii)-based metalloradical catalysis for five-membered cyclic sulfamides

Co(ii)-based metalloradical catalysis (MRC) proves effective for intramolecular 1,5-C–H amination of sulfamoyl azides under neutral and nonoxidative conditions, providing a straightforward approach to access strained 5-membered cyclic sulfamides with nitrogen gas as the only byproduct. The metallora...

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Detalles Bibliográficos
Autores principales:	Lu, Hongjian, Lang, Kai, Jiang, Huiling, Wojtas, Lukasz, Zhang, X. Peter
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2016
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5271564/ https://www.ncbi.nlm.nih.gov/pubmed/28138382 http://dx.doi.org/10.1039/c6sc02231f

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